5.4.3 Wind Suspension or Water Erosion
Contaminant mass can also be lost from
the source zone by removal of soil (which contains contamination) from
the upper surface of the zone by natural processes. Particles of contaminated
soil can be suspended in the air and moved away from the source zone by
wind action, or they can be dislodged from the soil surface by water erosion
and moved away from the source zone suspended in overland runoff. While
both of these processes are governed by unique mechanisms, the ultimate
mass loss flux equations for both processes have similar mathematical forms.
Therefore, both of these contaminant loss pathways will be discussed in
this one section, even though the resulting equations presented in this
section are strictly for mass loss when only one of these processes is
occurring.
First, consider scenarios where the soil is contaminated
all the way up to the soil surface. These surface removal processes then
strip off bulk soil from the top of the contaminant source zone (which
is exposed to the wind or the overland runoff water). Consequently, these
scenarios can be characterized by surface soil removal rates due to wind
suspension, S, and water erosion, E. These rates are defined as the depth
of surface soil lost per time (which is equivalent to the volume of surface
soil lost per time per area of surface). Because these processes strip
off a depth of the soil itself, they remove all contaminant that is contained
in the bulk soil. Therefore, the mass loss flux is not affected by how
the contaminant is partitioned between aqueous, solid-sorbent, vapor, or
NAPL phases. The contaminant mass flux to a surface soil removal pathway
is then given by
The volume of the source zone is given by
where h is the thickness of the contaminant source zone (cm).
Substituting Equation 5.69 into Equation 2.2, and then substituting
the resulting equation into Equation 5.68, we obtain
Note that the thickness, h, of the source zone is not a constant in
these cases, but instead decreases linearly with time because the surface
soil removal process is constantly stripping away soil from the top of
the zone. When this time dependence is explicitly written, the mass flux
equations for loss from the source zone by either wind suspension alone
or water erosion alone are given by
and
On the other hand, there can also be scenarios where the soil is not
contaminated all the way up to the soil surface. If a clean uncontaminated
soil layer exists above the contaminant source zone, these surface soil
removal processes will be stripping away clean soil. Therefore, the contaminant
mass flux is zero for wind suspension and water erosion as long as a clean
layer remains. However, as the clean layer is gradually removed, the contaminant
source zone may eventually become exposed. When the clean layer is completely
eroded away, mass fluxes to these two pathways will become non-zero according
to Equations 5.71 and 5.72.
Note, that deposition of clean soil particles onto the top of
the site (by either wind or water) can also be simulated by the module
by entering negative values of S or E. In these cases, the module sets
the contaminant mass flux for wind suspension and water erosion to zero.