2.5 OTHER VEGETABLE INGESTION
This exposure pathway uses the same model as the
leafy vegetable pathway except that parameters may be assigned different
numerical values representative of food crops that are not characterized
as leafy vegetables. This includes grains, root crops, and crops for which
the consumed food is generally not exposed directly to the depositing material.
The equations for the other vegetable pathway are the same as those for
the leafy vegetable pathway. The equations are repeated here for completeness,
with subscripts appropriate to the other vegetable pathway.
The pollutant deposition rates to croplands from
atmospheric transport and irrigation water application are evaluated using
the same equations as for the leafy vegetable pathway [Equation (18) for
irrigation deposition and Equation (25) for atmospheric deposition]. The
soil accumulation factor is also applied to the other vegetables pathway,
as defined by Equations (19) and (20).
When surface water is the source of irrigation water,
the correction for loss of pollutant during surface water transport is
made as indicated by Equation (3).
The plant contamination from irrigation deposition
onto edible parts of plants will result in a contamination level at harvest
that is estimated as follows:
(34)
where
CWDovi = pollutant i concentration in other vegetables
at time of harvest from water deposition onto plants (mg/kg or pCi/kg)
DPwi = deposition rate of pollutant i in irrigation water
to crops (mg/m2/d or pCi/m2/d)
TVov = translocation factor from plant surfaces to edible
parts of the plant for other vegetables (dimensionless)
rov = fraction of deposition retained on edible parts of
the other vegetable plant (dimensionless)
l ei = l
di + l w
l di = environmental
degradation and decay constant for pollutant i in soil (d-1)
l w = weathering decay constant
for losses from plant surfaces (d-1)
TCov = duration of the growing period for other vegetables
(d)
Yov = yield of other vegetables (kg/m2).
The plant concentration at the time of harvest for uptake from soil via
roots, following irrigation deposition, is estimated as follows:
(35)
where
CWRovi = pollutant i concentration in edible parts
of other vegetables at harvest from root uptake (mg/kg or pCi/kg)
FIov = fraction of year that irrigation occurs
for other vegetable crops (dimensionless)
SAFi = soil accumulation factor for the other vegetables
exposure duration for pollutant i (d).
and other terms are as previously defined.
The concentration in other vegetables is evaluated
as the sum of contributions for the two contamination routes: deposition
onto plants and root uptake from soil, as follows.
(36)
where
Covi = concentration of pollutant i in other vegetables
(mg/kg)
l gi = loss and decay rate constant
for pollutant i in closed water systems (d-1)
THov = holdup time between harvest of other vegetables and
consumption by humans (d)
and other terms are as previously defined.
The average daily dose from ingestion of chemical
pollutants (for irrigation water contamination) in other vegetables is
evaluated as follows:
(37)
where
Dovi = average daily dose from ingestion of other
vegetables (mg/kg/d)
Uov = ingestion rate of other vegetables by the exposed individual
(kg/d)
Fov= fraction of days per year that ingestion of other vegetables
occurs (dimensionless)
EDov = exposure duration for the other vegetable ingestion
pathway (yr)
ATovi = averaging time for other vegetable ingestion pathway
for exposure to pollutant i (yr)
BWov = body weight of individuals exposed by other vegetable
ingestion pathway (kg).
and Covi is as previously defined. The averaging time for noncarcinogenic
chemicals is set to the exposure duration, and the averaging time for carcinogenic
chemicals is fixed at 70 years.
For radioactive pollutants, the total lifetime dose
is evaluated as follows:
(38)
where
Dovi = total lifetime dose from ingestion of other
vegetables (rem)
DFgi = dose conversion factor for ingestion of radionuclide
i (rem/pCi)
and other terms are as previously defined.
For the atmospheric deposition pathway, the direct
deposition of pollutants from air onto edible parts of plants is estimated
by Equation (27), with parameters for the air pathway substituted for the
irrigation pathway as follows:
(39)
where
CADovi = pollutant i concentration in other vegetables
at time of harvest from atmospheric deposition onto plants (mg/kg or pCi/kg)
DPai = deposition rate from air to plants for pollutant i
(mg/m2/d or pCi/m2/d)
and other terms are as previously defined.
The soil accumulation factor is also applied to the
atmospheric deposition to soil route, as defined by Equations (19) and
(20). The plant concentration at the time of harvest for uptake from soil
via roots following atmospheric deposition is estimated, as follows:
(40)
where
CARovi = pollutant i concentration in edible parts
of other vegetables at harvest from root uptake (mg/kg or pCi/kg)
DPsi = annual average deposition rate of pollutant i to soil
from atmospheric transport and deposition (mg/m2/d or pCi/m2/d)
and other terms are as previously defined.
The concentration of pollutants in other vegetables
at the time of consumption is evaluated as the sum of contributions from
the two contamination routes: deposition onto plants and root uptake from
soil, as follows:
(41)
where
Covi = concentration of pollutant i in other vegetable
crops at the time of consumption (mg/kg or pCi/kg)
and other terms are as previously defined.
The average daily dose from ingestion of chemical
pollutants (for the atmospheric transport pathway) in other vegetables
is evaluated as follows:
(42)
where
Dovi = average daily dose from ingestion of other
vegetables (mg/kg/d)
EDov = exposure duration for the other vegetable ingestion
pathway (yr)
and other terms are as previously defined. The averaging time for noncarcinogenic
chemicals is set to the exposure duration, and the averaging time for carcinogenic
chemicals is fixed at 70 years.
For radioactive pollutants, the total lifetime dose
is evaluated as follows:
(43)
where Dovi = total lifetime dose from ingestion of other
vegetables (rem)
and other terms are as previously defined.
For the measured soil concentration pathway, the
exposure evaluation is performed for an initial soil concentration (measured)
with loss and decay during the exposure period. The following considerations
are included.
- Transport Medium:
- measured soil at the production location, Cmsi,
pCi/kg or mg/kg, expressed as the concentration at the start of the exposure
period
- Special Process:
-
- uptake by roots from soil to
- edible portions of plants
- loss of pollutants from soil by volatilization or decay
- loss of pollutants following harvest, prior to consumption by individuals
- Exposure Factors:
- rate of crop ingestion and exposure duration.
The average concentration is evaluated as the time
integral of the activity in the soil divided by the exposure duration,
as given by Equation (32).
The concentration in edible parts of plants from
root uptake from soil is evaluated as follows:
(44)
where terms are as previously defined.
The average daily intake from ingestion of chemicals
in leafy vegetables is evaluated using the plant concentration from Equation
(44) and intake Equation (42). For radionuclides, the ingestion dose is
evaluated using the plant concentration from Equation (44) and dose Equation
(43).